多面体低聚倍半硅氧烷的合成研究进展

胡建坤 已出版文章查询
胡建坤
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1 郁小芬 已出版文章查询
郁小芬
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1 陆阿定 已出版文章查询
陆阿定
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1 李娟 已出版文章查询
李娟
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2 龚淑玲 已出版文章查询
龚淑玲
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1浙江省海洋开发研究院,舟山 316021

2武汉大学化学与分子科学学院,武汉430072


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多面体低聚倍半硅氧烷(POSS)由于具有规整的立体结构、纳米尺寸、优良的相容性和修饰性,使其成为分子结构设计和材料改性的最佳选择之一.因此,POSS的合成引起了人们广泛的关注,深入研究它的合成方法与反应机理具有十分重要的学术意义和应用价值.本论文综述了POSS的合成研究进展(包括水解缩合法、官能团衍生法、缺角闭环法等),重点介绍了全同取代(T8R8)、单官能团(T8R7R')、多官能团(T8RnR'8-n)及半缩合POSS(T7)的制备方法与途径,并总结了POSS的合成经验及发展方向.

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语种: 中文   

基金国家自然科学基金(20772092)

关键词倍半硅氧烷 POSS 合成 制备


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